Ion Transfer Proceses across Liquid/Liquid Interfaces Promoted by Convective Flux.

N. WILKE; R. A. IGLESIAS, ; S. G. CHESNIUK,; S. A. DASSIE,; A.M.BARUZZI

CHEMICAL SOC JAPAN

Año: 2001 vol. 75 p. 1 - 1

onvective flux produced by stirring either the aqueous or the organic phase is proposed as a mechanistic tool tostudy the ion-transfer processes at ITIES. The dependence of the voltammetric response on the sweep rate and the rotationfrequency was used to differentiate the simple transfer of TEA+from the assisted transfer of K+by DB18C6 at awater 1,2-dichloroethane interface.