Resumen:
p style="text-align: justify;" class="MsoNormal">The active-pasive transition of silver
electrodes in solutions containing sulphate or chromate is described. The
formation of the silver salt layer takes place through a
dissolution-precipitation mechanism. The early stages of growth of the Ag2CrO4
films involve a three dimensional nucleation process with growth controlled by
diffusion of chromate ions. The overall rate of salt films growth in both
electrolytes is controlled by the resistance of the electrolyte in the pores of
the layer. Experimental data are compared with calculated curves for the
layer-pore resistance model.