Atmospheric Degradation of Fluoroesters (FESs) : Gas-Phase Reactivity Study Towards OH Radicals at 298K

M. B .BLANCO AND M.A.TERUEL

PERGAMON-ELSEVIER SCIENCE LTD

Año: 2007 p. 7330 - 7330

p class="NormalWeb" style="MARGIN: auto 0cm; LINE-HEIGHT: 200%; TEXT-ALIGN: justify">Using the relative technique, rate coefficients have been measured for the gas phase reactions of hydroxyl radicals with four fluoroacetates, methyl trifluoroacetate (CF3COOCH3), ethyl trifluoroacetate (CF3COOCH2CH3), methyl difluoroacetate (CF2HCOOCH3) and 2,2,2-trifluoroethyl trifluoroacetate (CF3COOCH2CF3). Experiments were carried out at 296