Kinetic study of the reactions of Cl atoms with a,b-unsaturated carbonyls compounds at atmospheric pressure and structure activity relations (SARs)

ELSEVIER SCIENCE BV

Año: 2009 vol. 479 p. 25 - 25

p class="MsoNormal" style="MARGIN: 0cm 0cm 0pt; LINE-HEIGHT: 200%; TEXT-ALIGN: justify">The kinetics of the reactions of Cl atoms with three unsaturated carbonyl compounds at 298 K and atmospheric pressure were investigated for the first time using the GC-FID technique. Rate coefficients(in cm3 molecule-1 s-1) of k1(Cl + CH2=CHC(O)CH2CH3) = (2.52 ± 0.3) x  10-10,