Gas-Phase Rate Coefficients for O(3P) + 2-chloropropene and O(3P) + 3-chloropropene reactions at 298K using a discharge flow tube

P. M. COMETTO, M. B. BLANCO, M.A.TERUEL, R.A.TACCONE AND S.I.LANE

ASOCIACIÓN QUÍMICA ARGENTINA

Año: 2005 vol. 93 p. 163 - 163

he kinetics of the O(3P) + CH2=CClCH3 and O(3P) + CH2=CHCH2Cl reactions werestudied at room temperature in a discharge flow tube system. The overall rate constantsbased on the measured afterglow reactions were (3.15 ± 0.17) × 10-12 and (1.35 ± 0.08) ×10-12 in units of cm3 molecule-1 s-1, respectively. The experiments were carried out underpseudo-first-order conditions with [O(3P)]o