Kinetics and mechanism of the Cl-initiated oxidation of 4-tert-butylcyclohexanone at atmospheric conditions: Reactivity, SARs and fate of the alkoxy radicals formed

BAPTISTA, ANDREA; BLANCO, MARÍA B.; GIBILISCO, RODRIGO G.; TERUEL, MARIANO A.

ATMOSPHERIC ENVIRONMENT

PERGAMON-ELSEVIER SCIENCE LTD

Año: 2023 vol. 294

1352-2310

he rate coefficient of the gas-phase reaction of 4-tert-butylcyclohexanone (4-TBCH) with Cl atoms was determined by the relative method in a Teflon collapsible chamber with GC-FID detection to be k4-TBCH= (2.84 ± 0.40) × 10−10 and in a glass photoreactor with in situ FT-IR detection to be k4-TBCH= (2.74 ± 0.64) × 10−10. As an average value of the GC-FID and FT-IR techniques, it is recommended k4-TBCH= (2.79 ± 0.34) × 10−10 (all values in cm3 molecule−1 s−1) at 298 K and 760 Torr. Reactivity trends were developed with respect to the nature and position of the substituents in the cycle of the Volatile Organic Compounds (VOCs) compared. On the other hand, Structure Activity Relationship (SAR) were performed and compared with the kinetic data obtained in the present work and used to predict the more favorable site of H abstraction in the cyclic ketone. In addition, the products formed under atmospheric conditions were identified for the first time by SPME/GC-