Hydrogen peroxide synthesis over metallic catalysts

P. PAREDES OLIVERA; E. M. PATRITO; HARRELL SELLERS

ELSEVIER SCIENCE BV

Lugar: Amsterdam; Año: 1994 vol. 313 p. 25 - 25

he energetics of the elementary reactions involved in the synthesis of hydrogen peroxide over noble metalcatalysts have been investigated using the bond order conservation-Morse potential approach (BOC-MP). Enthalpychanges as well as activation energies for forward and reverse reactions were calculated for the different elementarysteps which may occur by reaction of H, and 0, on the noble metal series Pd, Pt, Ag and Au. According to theBOC-MP model, under low surface coverage conditions the reaction proceeds along a water channel in which hydroxyl radicals are the main intermediates. No hydrogen peroxide is produced under these conditions. The model indicates that the formation of hydroxyl radicals should be blocked and adsorbed hydroxyls should be destabilized for the reaction to proceed along the hydrogen peroxide channel in which OOH radicals play a fundamental role. In the metal series investigated the production of H,O, is more favorable on gold and silver than on the other metal