Kinetic of the reactions of [p-nitrophenoxy(phenyl)carbene]pentacarbonylchromium(0) with aryloxide ions, hydroxide ion and water in aqueous acetonitrile. Concetated or stepwise?

CLAUDE F. BERNASCONI; MARTÍN E. ZOLOFF MICHOFF; ALEJANDRO M. GRANADOS; RITA H. DE ROSSI

American Chemical Society

Lugar: Washington; Año: 2007 vol. 72 p. 1285 - 1285

p class="MsoNormal" style="margin: 0cm 0cm 0pt;">The main question addressed in this paper is whether the nucleophilic substitution of the p-nitrophenoxy group in (CO)5CrdC(OC6H4-4-NO2)Ph (1-NO2) by a series of subs