Artículos
Título:
Distribution of ionic components between two immiscible solutions. Partition of weak bases
Autor/es:
GARCIA, J. I. ; FERNÁNDEZ, R.A., DASSIE, S.A., T. KAKIUCHI
Referencias:
Lugar: Holanda; Año: 2010 vol. 640 p. 42 - 42
Resumen:
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Theoretical aspects concerning the calculation of the distribution potential at the interface between two
immiscible electrolyte solutions are examined. In particular, we analyze the effect of the ratio between
the volumes of each phase (r) on the distribution potential for several systems with different levels of
complexity. First, we examine the effect of water autoprotolysis for a system composed of completely dissociated
electrolytes and weak bases. Finally, the effect of including the ion-pair formation on the potential
distribution is considered. In all cases, the algebraic expressions for the equilibrium distribution
potential