Facilitated ion transfer reactions across oil|water interfaces based on different competitive ligands

J.I. GARCÍA, R.A. IGLESIAS, S.A. DASSIE

Elsevier

Año: 2005 vol. 580 p. 255 - 255

font face="AdvPSTim" size="1"> In this paper, we present the general equations for facilitated ion transfer reactions across oiljwater interfaces based on different competitive ligands, i.e., the transfer of a cation that, under given conditions, is assisted by a mechanism that involves ligands exchange. The obtained results agree with the general voltammetric criteria reported by Girault and co-workers [F. Reymond, P.-A. Carrupt, H.H. Girault, J. Electroanal. Chem. 449 (1998) 49; F. Reymond, G. Lagger, P.-A. Carrupt, H.H. Girault, J. Electroanal. Chem. 451 (1998) 59] for the facilitated transfer of a unique cation assisted by a neutral ligand. The equations reported in this paper grant to simulate the system under all possible conditions. The results are interpreted for different zones determined b