Ion transfer processes across liquid|liquid interfaces promoted by convective flux

N. WILKE; R.A. IGLESIAS; S.G. CHESNIUK; S.A. DASSIE; A.M.BARUZZI

CHEMICAL SOC JAPAN

Año: 2002 vol. 75 p. 235 - 235

onvective flux produced by stirring either the aqueous or the organic phase is proposed as a mechanistic tool to study the ion-transfer processes at ITIES. The dependence of the voltammetric response on the sweep rate and the rotation frequency was used to differentiate the simple transfer of TEA + from the assisted transfer of K + by DB18C6 at a water 1,2-dichloroethane interface.