BAPTISTA ANDREA
Artículos
Título:
FTIR kinetic study of the reactions of Gamma-caprolactone and Gamma-heptalactone initiated by Cl and OH radicals at 298 K and atmospheric pressure
Autor/es:
ANDREA BAPTISTA
Revista:
CHEMICAL PHYSICS LETTERS
Editorial:
ELSEVIER SCIENCE BV
Referencias:
Lugar: Amsterdam; Año: 2020 vol. 765 p. 138313 - 138313
ISSN:
0009-2614
Resumen:
ate coefficients were determined for the reactions of the furanones (C6H10O2) (C7H12O2) with OH radicals (k1 and k2) and with Cl atoms (k3 and k4) at 298 K, to be(in cm3 molecule 1 s 1): k1 = (6.4 ± 1.4) × 10 12, k2 = (8.8 ± 1.9) × 10 12, k3 = (1.30 ± 0.41) × 10 10, k4 = (1.70 ± 0.34) × 10 10, respectively. kOHcorrelates with kCl and SAR show C5 as the favored site of H abstraction.
