Atmospheric Oxidation of Vinyl and Allyl Acetate: Product Distribution and Mechanisms of the OH-Initiated Degradation in the Presence and Absence of NOx

M. B. BLANCO, I. BEJAN, I. BARNES, P. WIESEN AND MARIANO A. TERUEL

AMER CHEMICAL SOC

Lugar: Washington; Año: 2012 vol. 46 p. 8817 - 8817

p style="TEXT-ALIGN: justify; LINE-HEIGHT: 200%; MARGIN: 0cm 0cm 0pt">The products formed from the reactions of OH radicals with vinyl acetate and allyl acetate have been studied in a 1080 L quartz-glass chamber in the presence and absence of NOx using in situ FTIR spectroscopy to monitor the reactant decay and product formation. The yields of the primary products formed in the reaction of OH with vinyl acetate were: formic acetic anhydride (84