Atmospheric photodegradation of ethyl vinyl ketone and vinyl propionate initiated by OH radicals

M.B.BLANCO AND M. A. TERUEL

ELSEVIER SCIENCE BV

Lugar: Amsterdam; Año: 2011 vol. 502 p. 159 - 159

p>Rate coefficients for the reactions of hydroxyl radicals with ethyl vinyl ketone and vinyl propionate were determined at 298K and atmospheric pressure. A collapsible chamber with gas chromatography was used to perform relative kinetic determinations. The room temperature rate coefficients (in cm3 molecule-1 s-1) were: k1(OH + CH2=CHC(O)CH2CH3) = (2.90 ± 0.79) x 10-11 and  k