ZOLOFF MICHOFF MARTIN EDUARDO
Artículos
Título:
Hydrolysis of Fischer Carbene Complexes. Steric Effects of the p-Donor Group
Autor/es:
MARTIN E. ZOLOFF MICHOFF, RITA H. DE ROSSI, ALEJANDRO M. GRANADOS
Revista:
JOURNAL OF ORGANIC CHEMISTRY
Editorial:
ACS Publications
Referencias:
Lugar: Washington DC; Año: 2006 vol. 71 p. 2395 - 2395
ISSN:
0022-3263
Resumen:
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Rate constants for the hydrolysis of Fischer carbenes (CO)5CrdC(OR)Ph (R ) n-propyl, neopentyl, isopropyl, and menthyl) in 50% MeCN-50% water (v/v) at 25 °C are reported. The rate constants for the addition of -OH to the carbene carbon are 5.3, 3.7, 0.84, and 0.01 M-1
