Bis(trifluoromethyl) dicarbonate, CF3OC(O)OC(O)OCF3

P. GARCÍA; H. WILLNER; M. BURGOS PAC; G.A. ARGÜELLO

JOURNAL OF FLUORINE CHEMISTRY

Año: 2005 vol. 126 p. 984 - 984

0022-1139

font face="AdvP41153C" size="1"> The synthesis of the new compound, bis(trifluoromethyl)dicarbonate, CF3OC(O)OC(O)OCF3, is carried out by reduction of bis(trifluoromethyl) trioxidicarbonate with excess of CO at 0 8C. The product is characterized by IR, Raman, 13C and 19F NMR spectroscopy and its properties are compared with those of the other members of the series CF3OC(O)OxC(O)OCF