The Influence of magnetic field on the photochemical reactivity of coordination complexes: Photophysics and photochemistry of Chromiun (III) Polipiridine and Hexacyanocobaltate(III) complexes."

G. FERRAUDI; GERARDO A. ARGUELLO; M. FRINK

JOURNAL OF PHYSICAL CHEMISTRY

Año: 1987 vol. 91 p. 64 - 64

0022-3654

p class="MsoNormal" style="MARGIN: 0cm 0cm 0pt; LINE-HEIGHT: normal; mso-layout-grid-align: none">Intense magnetic fields, H > 10 kG, induce changes in the absorption and emission spectra of the long-lived doublet excited states in Cr(II1) polypyridine complexes and increase the rate of excited-state relaxation by ca. 10%. Similar effects were detected with polycrystalline samples of K,[CO(CN)~b] between