Resumen:
p class="MsoNormal" style="MARGIN: 0cm 0cm 0pt">The herbicide trifluralin (I) (N,N,-di-n-propyl-2,6-dinitro-4-trifluoromethylaniline) decomposes, by the action of UV-vis ligth (l > 300 nm), to several products, the most important (because they give subsequent photochemical reactions) being N-n-propyl-2,6-dinitro-4-trifluoromethylaniline (VI), 2-ethyl-7-nitro-5-trifluoromethyl-1H-benzimidazole 3-oxide (VII) and 2,6-dinitro-4-trifluoromethylaniline (XII). The time evolution of degradation of trifluralin (I) and the aforementioned three main photoproducts was studied in water and acetonitrile as solvents. The pseudo-first order rate constants allow one to calculate the branchin ratios for some of the reactions involved. The preference for either N-dealkylation or cyclization depends on the solvent employed. Dissolved oxygen