Transition from Hund¡¦s coupling case a to case b in CaF (A(2?n?À?Ç)) obtained from the Ca(3PJ) + CF2Cl2 ?_ CaF(A(2?À?Ç)) + CFCl2 reaction induced by collisional energy

G. A. PINO; C. A. RINALDI; J. C. FERRERO

ELSEVIER SCIENCE BV

Año: 2001 vol. 349 p. 463 - 463

font face="AdvPSTim" size="1"> The emision spectra of CaF(A2P) produced in the Ca(3P) + CF2Cl2 -> CaF(A,2P) + CFCl2 reaction has been measured at two different collision energies, showing evidence for transition from Hund´s couplin case (a)  at the lower collision energie to case (b) at the higher one.