Photodissociation Dynamics of Dimethyl Sulfoxide-d6 at 210 nm: Experimental Evidence for a Prompt Anisotropic CD3 Channel

G. A. AMARAL; I. TORRES; G. A. PINO; F. J. AOIZ; L. BAÑARES

ELSEVIER SCIENCE BV

Año: 2004 vol. 386 p. 419 - 419

font face="AdvPSTim" size="1"> The photodissociation of dimethyl sulfoxide-d6 has been studied at 210 nm by REMPI-TOFMS spectroscopy. The anisotropy of a fast CD3 dissociation channel has been characterized for the first time. This channel corresponds to the formation of CD3 and electronically excited CD3SO(