Effect of the intermolecular hydrogen bond conformation on the structure

A. N. OLDANI; J. C. FERRERO; G. A. PINO *

ROYAL SOC CHEMISTRY

Año: 2009 vol. 11 p. 10409 - 10409

font size="1" face="AdvTimes"> The structure and reactivity of p-CrOH(NH3)2 and p-CrOH(H2O)(NH3) complexes were studied using mass resolved one colour REMPI and LIF spectroscopy together with DFT calculations. At the excitation energy of this work, the S1 state of p-CrOH(NH3)2 shows a sub-nanosecond lifetime, as determined by time resolved LIF spectra, as a consequence of an hydrogen transfer process that results in