Gas-phase reactivity study of O(3P) atoms with trans-CHCl=CHCl and CHCl=CCl2 at 298 K. Comparison to reactions with some other substituted ethenes.

JOHN WILEY & SONS INC

Lugar: Nueva York-USA; Año: 2001 vol. 33 p. 415 - 415

h5 style="LINE-HEIGHT: 200%">AbstractAbsolute rate coefficients for the gas-phase reactions of trans-dichloroethene and trichloroethene with O(3P) atoms have been measured at 298 K using a discharge flow tube coupled to a chemiluminescence detection system. The observed rate constant values are (2.2 ± 0.4) x 10?13 and (1.4