Absolute rate constants for the gas-phase reactions of O(3P) atoms with CF2=CFCl and (E/Z)-CFCl=CFCl at 298 K. Reactivity trends of the halogen substituted ethenes series.

JOHN WILEY & SONS INC

Lugar: Nueva York-USA; Año: 2004 vol. 36 p. 525 - 525

h3 style="LINE-HEIGHT: 200%; TEXT-ALIGN: justify">Abstract Absolute rate coefficients for the gas-phase reactions of  CF2=CFCl and (E/Z)-CFCl=CFCl with O(3P) atoms have been measured at 298 K using a discharge flow tube coupled to a chemiluminescence detection system. The observed rate constant values are (4.5 ±