Gas-phase rate coefficients for the O(3P) reactions with 2-chloropropene and 3-chloropropene at 298K using the discharge flow technique

ASOCIACIÓN QUÍMICA ARGENTINA

Lugar: Buenos Aires; Año: 2005 vol. 93 p. 163 - 163

h4 style="LINE-HEIGHT: normal; MARGIN: 6pt 0cm">Abstract The kinetics of the O(3P) + CH2=CClCH3 and O(3P) + CH2=CHCH2Cl reactions were studied at room temperature in a discharge flow tube system. The overall rate       constants based on the measured afterglow reactions were (3.15 ± 0.17)