Absolute determinations of the addition rate constants for the reactions of O(3P) atoms with halogenated propenes and butenes.

JOHN WILEY & SONS LTD

Lugar: Nueva York-USA; Año: 2005 vol. 18 p. 142 - 142

ABSTRACT:             The kinetics of the reactions of O(3P) atoms with CF3CH=CH2, CF3CCl=CCl2, CF3CF=CClCF3 and CF3CCl=CClCF3 were studied at 298 K using a discharge flow tube system. This is the first absolute kinetic study of these reactions. The overall rate constants based on the measured afterglow reactions were (3.4 ±