Absolute rate determinations and temperature dependences of the gas-phase reactions of O(3P) with halogenated propenes

ELSEVIER SCIENCE BV

Lugar: Londres - UK; Año: 2006 vol. 417 p. 480 - 480

Abstract The rate constants for the gas-phase reactions of ground state oxygen atoms with  CF3CH=CH2 (1), CF3CF=CF2 (2) and CF3CCl=CCl2 (3) have been measured directly using a discharge flow tube employing the O(3P) chemiluminescence titration method. The experiments were carried out under pseudo-first-order conditions with  [O(3P)]0