Gas-Phase Reactions of Cl Atoms with Hydrochloroethers: Relative Rate Constants and their Correlation with Substituents? Electronegativities.

JOHN WILEY & SONS LTD

Lugar: Nueva York-USA; Año: 2008 vol. 21 p. 393 - 393

p class="MsoNormal" style="MARGIN: 0cm 0cm 0pt; mso-layout-grid-align: none">Rate constants for the reactions of Cl atoms with CH3OCHCl2 and CH3OCH2CH2Cl were determined at 296±2) K and atmospheric pressure using synthetic air as bath gas. Decay rates of these organic compounds were measured relative to the following reference compounds: CH2ClCH2Cl and n-C5H12. Using rate constants of 1.33x10-12 and 2.52±