Absolute rate determinations and temperature dependences of the gas-phase reactions of O(3P) with halogenated propenes

PABLO M. COMETTO, MARIANO A. TERUEL, RAÚL A. TACCONE AND SILVIA I. LANE

Elsevier

Año: 2006 vol. 417 p. 480 - 480

div style="BORDER-RIGHT: medium none; PADDING-RIGHT: 0cm; BORDER-TOP: medium none; PADDING-LEFT: 0cm; PADDING-BOTTOM: 1pt; BORDER-LEFT: medium none; PADDING-TOP: 0cm; BORDER-BOTTOM: windowtext 0.75pt solid"> The rate constants for the gas-phase reactions of ground state oxygen atoms with  CF3CH=CH2 (1), CF3CF=CF2 (2) and CF3CCl=CCl2 (3) have been measured directly using a discharge flow tube employing the O(3P) chemiluminescence titration method. The experiments were