Gas-phase rate coefficients for the O(3P) reactions with 2-chloropropene and 3-chloropropene at 298K using the discharge flow technique

P.M. COMETTO, M. B. BLANCO, M. A. TERUEL, R. A. TACCONE AND S. I. LANE

Asociación Química Argentina

Lugar: Bs.As-Argentina; Año: 2005 p. 163 - 163

p class="MsoNormal" style="MARGIN: 6pt 0cm; TEXT-INDENT: 35.4pt; LINE-HEIGHT: 200%; TEXT-ALIGN: justify">The kinetics of the O(3P) + CH2=CClCH3 and O(3P) + CH2=CHCH2Cl reactions were studied at room temperature in a discharge flow tube system. The overall rate       constants based on the measured afterglow reactions were (3.15 ± 0.17)