Absolute rate constants for the gas-phase reactions of O(3P) atoms with CF2=CFCl and (E/Z)-CFCl=CFCl at 298 K. Reactivity trends of the halogen substituted ethenes series

MARIANO A. TERUEL, RAUL A. TACCONE AND SILVIA I. LANE

Wiley

Lugar: NYC-USA; Año: 2004 vol. 36 p. 525 - 525

p class="MsoNormal" style="MARGIN: 0cm 0cm 0pt; LINE-HEIGHT: 200%; TEXT-ALIGN: justify">Absolute rate coefficients for the gas-phase reactions of  CF2=CFCl and (E/Z)-CFCl=CFCl with O(3P) atoms have been measured at 298 K using a discharge flow tube coupled to a chemiluminescence detection system. The observed rate constant values are (4.5 ±