Resolution of CpMo(NO)(Þ3-2-methallyl) complexes and their enantioselective reactions with an aldehydes

J.W. FALLER; J.T. NGUYEN; W. ELLIS; MR. MAZZIERI

AMER CHEMICAL SOC

Lugar: Washington; Año: 1993 vol. 12 p. 1434 - 1434

font size="4" face="Courier New"> (R-) and (S)-CpMo( NO)(+methallyl) (( S)- (+ )-10-camphorsulfonate) (Cp = cyclopentadienyl) have been prepared and separated. This provides a route for resolution of the chiral molybdenum center and allows the isolation of enantiomerically pure CpMo(NO)(v3-methallyl)X (X = C1,Br, I) complexes.   Reaction of