Strain energy effect on the reactivity of bridgehead halides in electron transfer reactions

PIERINI A. B.; SANTIAGO A. N.; ROSSI R. A.

PERGAMON-ELSEVIER SCIENCE LTD

Año: 1991 vol. 47 p. 941 - 941

p class="MsoNormal" style="MARGIN: 0cm 0cm 0pt; mso-layout-grid-align: none">We here report MNDO and AMl calculations of bridgehead compounds witch indicate that an increase in their angular strain is accompanied by more negative reduction potentials as masured thorough their LUMO energies.