Atmospheric Degradation of CH2=C(CH3)C(O)OCH3 initiated by OH Radicals: Mechanistic study and quantification of CH3C(O)C(O)OCH3 at NOx free air.

GIBILISCO, R. G.; JORGE G. URANGA; ANA N. SANTIAGO; TERUEL, M. A.

AMER CHEMICAL SOC

Lugar: Washington; Año: 2015 vol. 1 p. 1 - 1

p style="TEXT-ALIGN: justify; LINE-HEIGHT: 150%; TEXT-INDENT: 35.4pt; MARGIN: 0cm 0cm 0pt; TEXT-AUTOSPACE: ideograph-numeric" class="MsoNormal">The product distribution of the gas-phase reaction of OH radicals with methyl methacrylate (CH2=C(CH3)C(O)OCH3, MMA) in the absence of NOx was studied at 298 K and atmospheric pressure of air. The experiments were performed in a Teflon chamber using solid phase microextraction (SPME) with GC-MS and GC-FID for product identification and quantification, respectivel