Triorganostannylation of Halo- and Dihaloadamantanes and 5-Chloro-2-adamantanone in Liquid ammonia by the SRN1 Mechanism. Relative Reactivity of Nucleophiles and Bridgehead Halides.

SANTIAGO A. N.; TOLEDO C. A.; ROSSI R. A.

AMER CHEMICAL SOC

Año: 2002 vol. 67 p. 2494 - 2494

font face="Times New Roman" size="2"> The reactions of 1-bromo-, 1-iodo-, 2-bromo-, 1,3-dibromo-, and 1,4-dibromoadamantane with Me3Snions were studied in liquid ammonia. The photostimulated reaction of 1-haloadamantane (1-XAd, X ) Br, I) or 2-BrAd with Me3Sn-