Reactions of 1,3-Dihaloadamantanes with Carbanions in DMSO:

LUKACH A. E.; SANTIAGO A. N.; ROSSI R. A.

AMER CHEMICAL SOC

Año: 1997 vol. 62 p. 4260 - 4260

font face="Times New Roman" size="2"> 2-Bromoadamantane (2-BrAd) reacted in liquid ammonia under irradiation with diphenylphosphide (Ph2P-) ions whereas 2-chloroadamantane (2-ClAd) did not under the same experimental conditions. However, 2-ClAd yielded 2-(trimethylstannyl)adamantane in its photostimulated reaction with trimethylstannyl (Me3Sn