Reactions of Halo- and Dihaloadamantanes with Nitromethane Anion by the SRN1 Mechanism.

SANTIAGO A. N.; TOLEDO C. A.; ROSSI R. A.

John Wiley & Sons, Ltd.

Lugar: Hoboken, New Jersey; Año: 2003 vol. 16 p. 413 - 413

font face="Times-Roman" size="2"> ABSTRACT: The reactions of 1-bromo-, 2-bromo-, 1,3-dibromo- and 1,4-dibromoadamantane with -CH2NO2 anions were studied in DMSO and in liquid ammonia. The photostimulated reaction of 1-haloadamantane (1-AdX, X = Br, I) or 2-AdBr with CH2NO2 anions gave good yields of the substitution product 1-AdCH2NO2 and 2-AdCH