Resumen:
he one-pot synthesis of dibenzo[b,d]azepin-7-one (3) was selectively achieved from 1-phenacyl-1,2,3-benzotriazole (1) using the catalytic !ash vacuum pyrolysis (cfvp) methodology. Catalysts with the scheelite structure ABO4 (A = Ca2+, Sr2+, Ba2+ and B = Mo6+, W6+) and fergusonite BiVO4 were explored in this new catalytic reaction. These oxides promoted high conversion of starting material at lower temperatures than those observed for noncatalytic reactions. The chemical nature of A and B cations in the scheelite structure showed a strong inluence on the formation toward the desired azepinone. In addition, the catalyst?s morphology had a significant influence on the course of the cfvp reaction.