Crystal and magnetic structures and cations distributions of Mn2-xV1+xO4 spinels (x=0, 1/3 and 1)

ELISA V. PANNUNZIO MINER; JUAN M. DE PAOLI; RODOLFO D. SANCHEZ; RAÚL E. CARBONIO

Elsevier

Año: 2009 vol. 44 p. 1586 - 1586

e synthesized the spinel-type compounds belonging to the Mn2-xV1+xO4 series with x = 0, 1/3 and 1 as polycrystalline powders. Crystal and magnetic structures were refined using synchrotron X-ray and neutron powder diffraction. At 300 K all members crystallize in the cubic system, space group Fd-3m, and show a structural transition at low temperature, changing to a tetragonal symmetry (space group I41/amd). Cations distributions between octahedral and tetrahedral sites were refined from neutrons diffraction (ND) data and explained based on crystal field stabilization energies (CFSE) and ionic radii.The magnetic unit cell is the same as the crystallographic one, having identical symmetry relations. The magnetic structure was refined as an arrangement of collinear spins, antiferromagnetically ordered, parallel to the c-axis of the unit cell. The refined site magnetic moments are smaller than those obtained from hysteresis cycles of the M vs. H measurem