Synthesis, DFT Calculations of Structure, Vibrational and Thermal Decompositions Studies of the Metal Complex Pb[Mn(C3H2O4)2(H2O)2]

DIEGO M. GIL; RAÚL E. CARBONIO ; MARÍA INÉS GÓMEZ

PERGAMON-ELSEVIER SCIENCE LTD

Lugar: Amsterdam; Año: 2015 vol. 141 p. 233 - 233

!--[if gte mso 9]> The metallo-organic complex Pb[Mn(C3H2O4)2(H2O)2] was synthesized and characterized by IR and Raman spectroscopy and powder X-ray diffraction methods. The cell parameters for the complex were determined from powder X-ray diffraction using the autoindexing program TREOR, and refined by the Le Bail method with the Fullprof program. A hexagonal unit cell was determined with a = b = 13.8366(7) Å, c = 9.1454(1) Å, gamma =120o. The DFT calculated geometry of the complex anion [Mn(C3H