ORTIZ CRISTINA SUSANA
Artículos
Título:
SYNTHESIS OF BENZYLIC IMIDYL DERIVATIVES OF PYRIDINE UNDER PHASE TRANSFER CATALYSIS
Autor/es:
A. R. SUÁREZ, M. J. FUMAROLA, B. V. ARGÜELLO, C. S. ORTIZ Y A. G. SUÁREZ.
Revista:
Anales de la Asociación Química Argentina
Editorial:
Anales de la Asociación Química Argentina
Referencias:
Año: 1987 p. 485 - 485
ISSN:
0365-0375
Resumen:
romine atoms of 2-bromomethyl-4,6-dimethylpyridine (I); 4-bromomethyl-2,6-dimethylpyridine (II) and 2-bromomethyl-3,6-dimethylpyridine (III) were substituted by the imidyl group of phtalimide (I; II; III; a), saccharin (I; II;III; b) and 5,5-dimethylhydantoin (I; II; III; c). Reaction were carried out under solid-liquid phase transfer catalysis (S/L P.T.C) with tetra-nor-butylammonium bromide (TBAB) as catalyst in toluene or chloroform as solvent. The isolation and purification procedures of (I) and (II) and (III) are also reported. Physical properties and spectral data of (I-III) compounds are informed.