Reactivity Comparison of D-Glucose-Derived Dienophiles. Analysis of the Conformational and Electronic Properties.

PELLEGRINET, S.C.; BAUMGARTNER, M.T.; SPANEVELLO, R.A.

MOLECULAR DIVERSITY PRESERVATION INTERNATIONAL-MDPI

Año: 2000 vol. 5 p. 451 - 451

emiempirical calculations were performed to carry out a conformational analysis for carbohydrate-derived dienophiles 1-4. For a,b-unsaturated carbonylic compounds 2-4, a good correlation between Diels-Alder reactivity with calculated values for LUMO energies was observed.