Mechanism of the alkaline hydrolysis of O-ethyl S-(2,4,6-trinitrophenyl) thio- and dithio-carbonates

ENRIQUE CASTRO; MARIA CUBILLOS; JOSE SANTOS; ELBA INES BUJ¨¢N; M. VIRGINIA REMEDI; MARIANA ADELA FERNÁNDEZ; RITA HOYOS DE ROSSI

The Royal Society of Chemistry

Lugar: Cambridge; Año: 1999 vol. 2 p. 2603 - 2603

span style="LINE-HEIGHT: 115%; FONT-FAMILY: "Calibri","sans-serif"; FONT-SIZE: 11pt; mso-fareast-font-family: Calibri; mso-bidi-font-family: "Times New Roman"; mso-ansi-language: EN; mso-fareast-language: EN-US; mso-bidi-language: AR-SA" lang="en">The alkaline hydrolysis of O-ethyl S-(2,4,6-trinitrophenyl) thio- and dithiocarbonates, 1 and 2, respectively, were studied kinetically in 5% dioxane in water, at 25.0 ¡ãC, and ionic strength 0.2 mol dm¨C3