Deciphering Solvation Effects in Aqueous Binary Mixtures by Fluorescence Behavior of 4-Aminophthalimide: The Comparison Between Ionic Liquids and Alcohols as Cosolvents

CROSIO, MATIAS A.; SILBER, JUANA J.; MORAN VIEYRA, F. EDUARDO; FALCONE, R. DARÍO; BORSARELLI, CLAUDIO. D.; CORREA, N. MARIANO

JOURNAL OF PHYSICAL CHEMISTRY B - (Print)

AMER CHEMICAL SOC

Lugar: Washington; Año: 2021 vol. 125 p. 13203 - 13203

1520-6106

onic liquids (ILs) have received attention for many years due to them being very promising as green solvent substitutes, but they are not fully understood, especially their behavior dissolved in other solvents, for example, water. Thus, the goal of this contribution is to show insight into the different IL?water mixtures interaction. In this way, two protic ILs (PILs), ethylammonium nitrate (EAN) and 1-methylimidazolium acetate (MIA), mixed with water were investigated. To study the PILs?water interaction, the unique spectroscopical behavior in water of the molecular probe 4-aminophthalimide (4-AP) was used. 4-AP emission spectra show hypsochromic shifting by changing the excitation wavelength and, using time-resolved spectroscopy, can be detected by a blue shifting with time. Also, the water mixture of an aprotic IL, 1-methyl-3-butylimidazolium tetrafluoroborate (bmimBF4), and three alcohols, methanol (MeOH), 2-propanol (2-PrOH), and t-butanol (t-BOH), were investigated for compariso