- “Effect of the Crosslinking Agent on the Formation of Porous Networks in HEMA Copolymers".

C. GOMEZ; C. ALVAREZ; M. STRUMIA

POLYMER

Elsevier

Lugar: Leeds (Reino Unido); Año: 2004 vol. 45 p. 6189 - 6189

0032-3861

p class="MsoNormal" style="MARGIN: 0cm 0cm 0pt; TEXT-INDENT: 35.4pt; LINE-HEIGHT: 200%; TEXT-ALIGN: justify">New copolymers of ethylene glycol dimethacrylate / 2-hydroxyethyl methacrylate [poly (EGDMA-co-HEMA)], 2, 2', 2''- nitrilotriethyl triacrylate / 2-hydroxyethyl methacrylate [poly (NTETA-co-HEMA)] and pentaerythritol tetraacrylate / 2-hydroxyethyl methacrylate [poly (PETA-co-HEMA)] were obtained by suspension polymerization at 70 °C or 85 °C, using cyclohexane (Cyc) as porogen. In this work, the influence of the crosslinking agent (di, tri, or tetravinyl monomer) on the morphology of the polymeric networks was investigated. Swelling studies, Fourier Transform Infrared (FTIR) and mercury intrusion porosimetry, demonstrated that when both the vinyl groups number and molecular chain length between double bonds of the crosslinking agent decreased, networks with high porosity and crosslinking degree were generated.